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Synlett 2008(14): 2204-2208
DOI: 10.1055/s-2008-1078254
DOI: 10.1055/s-2008-1078254
LETTER
© Georg Thieme Verlag
Stuttgart ˙ New York
Iodine-Catalyzed Allylic Alkylation of Thiols with Allylic Alcohols
Weitere Informationen
Received
2 July 2008
Publikationsdatum:
13. August 2008 (online)
Publikationsverlauf
Publikationsdatum:
13. August 2008 (online)
Abstract
An efficient iodine-catalyzed allylic alkylation of a wide variety of aryl and alkyl thiols with allylic alcohols is reported herein. The reaction is operationally straightforward, tolerant to air and moisture, and proceeds under very mild conditions at room temperature in good to excellent yields (50-92%).
Key words - allylic alcohols - allylic thioethers - alkyl and aryl thiols - carbon-sulfur bond formation - molecular-iodine catalysis
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