Electrochemical Aromatization of Dihydroazines: Effect of Chalco­genophosphoryl (CGP) Substituents on Anodic Oxidation of 9-CGP-9,10-dihydroacridine

Abstract

The effect of chalcogenophosphoryl fragments on the anodic oxidation of 9-chalcogenophosphoryl-9,10-dihydroacridines was studied in detail. The data of X-ray structural analyses, quantum chemical calculations, and cyclic voltammetry measurements obtained for these compounds provide an explanation of the observed features. The direct electrochemical phosphorylation of acridine was first carried out successfully.

Key words

electrochemical phosphorylation - anodic oxidation - C–H functionalization - green chemistry - acridine

Publication History

Received: 01 March 2021

Accepted after revision: 31 May 2021

Accepted Manuscript online:
31 May 2021

Article published online:
21 June 2021

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