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Synthesis 2021; 53(23): 4327-4340
DOI: 10.1055/a-1533-3597
DOI: 10.1055/a-1533-3597
short review
Recent Advances in Visible-Light-Promoted Copper Catalysis in Organic Reactions
This work was financially supported by the National Natural Science Foundation of China (NSFC-22071073, 21772218, and 21821002), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB20000000), and the State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry.
Abstract
In recent years, visible-light-mediated copper photocatalysis has emerged as an attractive strategy for the diverse construction of basic bonds in an ecologically benign and cost-effective fashion. The intense activity in these areas has been stimulated by the distinctive properties of copper photocatalysts and has led to the rapid development and expansion of their applications. In this review, we focus on a series of significant achievements in the use of copper complexes as standalone photocatalysts in organic reactions to exhibit their high flexibility and potential in synthetic chemistry.
1 Introduction
2 Redox Coupling Reactions
2.1 Carbon–Nitrogen Redox Coupling Reactions
2.2 Carbon–Carbon Redox Coupling Reactions
3 Oxidative Coupling Reactions
4 Difunctionalization of Olefins
5 C–H Bond Functionalization
6 Radical Alkylation of Imines
7 Conclusions and Outlook
Key words
visible-light-mediated - copper photocatalysis - cross-coupling - asymmetric - functionalizationPublication History
Received: 10 April 2021
Accepted after revision: 22 June 2021
Accepted Manuscript online:
22 June 2021
Article published online:
27 July 2021
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