Nickel Hydride Catalyzed Remote Hydroarylation of Olefins

Yuli He; Ran Tao; Shaolin Zhu

doi:10.1055/a-1637-9308

Synlett, Inhaltsverzeichnis

Synlett 2022; 33(03): 224-230
DOI: 10.1055/a-1637-9308

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Nickel Hydride Catalyzed Remote Hydroarylation of Olefins

Yuli He ‡

^aState Key Laboratory of Coordination Chemistry, Chemistry and Biomedicine Innovation Center (ChemBIC), Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. of China

,

Ran Tao‡

^aState Key Laboratory of Coordination Chemistry, Chemistry and Biomedicine Innovation Center (ChemBIC), Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. of China

^bDepartment of Chemistry, New York University, New York, 10003, USA

,

Shaolin Zhu ∗

^aState Key Laboratory of Coordination Chemistry, Chemistry and Biomedicine Innovation Center (ChemBIC), Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, P. R. of China

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Abstract

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Abstract

Metal hydride catalyzed remote hydrofunctionalization has attracted extensive attention in the past decade, as it provides a complementary approach for selective functionalization of remote C(sp³)–H bonds. Recently, a wide variety of olefinic remote hydrofunctionalization reactions have been realized through the synergistic combination of NiH-catalyzed chain-walking and Ni-catalyzed cross-coupling. In this Account we discuss our recent achievements in the remote hydroarylation of olefins and in asymmetric hydroarylation.

1 Introduction

2 NiH-Catalyzed Remote Hydroarylation

3 Progress in Asymmetric Catalysis

4 Conclusion

Key words

nickel catalysis - nickel hydride - chain-walking - C–H functionalization - hydroarylation - alkene - asymmetric catalysis

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Referenzen

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