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Synthesis 2022; 54(03): 565-569
DOI: 10.1055/a-1648-2821
DOI: 10.1055/a-1648-2821
short review
Biaryl Synthesis via Electrooxidative Transition-Metal-Catalyzed C–H Activation
Funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany’s Excellence Strategy – EXC-2033–390677874 – RESOLV, SFB/TRR88 3MET, and FOR 982/1 UNODE. We thank the Bundesministerium für Bildung und Forschung (BMBF) and the state of Nordrhein-Westfalen (NRW) (Center of Solvation Science, ZEMOS).
‡ Evonik Chair of Organic Chemistry
Abstract
The use of electricity as an inexpensive and waste-free oxidant opens up new opportunities for the development of sustainable C–H functionalization reactions. Herein we summarize recent advances in the synthesis of biaryls through electrooxidative processes involving transition-metal-catalyzed ortho-directed C–H activation. A particular focus is set on electrooxidative C–H/C–M couplings and dehydrogenative couplings.
1 Introduction
2 Electrooxidative C–H/C–M Couplings
3 Electrooxidative C–H/C–H Couplings
4 Conclusion and Outlook
Key words
electrochemistry - C–H activation - directing groups - transition-metal catalysis - biarylsPublication History
Received: 17 August 2021
Accepted after revision: 17 September 2021
Accepted Manuscript online:
17 September 2021
Article published online:
27 October 2021
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