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Synthesis 2022; 54(08): 1877-1907
DOI: 10.1055/a-1684-0031
DOI: 10.1055/a-1684-0031
review
Synthesis and Reactions of Borazines
I.N. thanks DST, India (GAP 162039) for funding.
Abstract
Given the wide array of current applications of borazine-based materials, synthetic access to these compounds is of importance. This review summarizes the many ways of preparing borazines and its carbo-substituted analogues. In addition, the functionalization of borazines is covered. The synthesis of molecules incorporating more than one borazine units as well as aspects of unsymmetrically substituted borazines are not included. The literature has been covered comprehensively until the end of 2020.
1 Introduction: Structure and Properties of Borazine
2 Synthesis of Parent Borazine
3 Synthesis of N-Substituted Borazines
4 Synthesis of B-Halo/B-Halo-N-Substituted Borazines
5 Synthesis of B-Substituted Borazines
6 Synthesis of Polycyclic Borazines Containing One Borazine Ring
7 Modifications or Hydrolysis of the Borazine Ring
8 Borazine Metal Complexes
9 Outlook and Conclusion
Publication History
Received: 04 July 2021
Accepted after revision: 02 November 2021
Accepted Manuscript online:
02 November 2021
Article published online:
24 February 2022
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For the X-ray crystallographic determination, see: