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Synthesis 2022; 54(22): 5026-5034
DOI: 10.1055/a-1846-5598
DOI: 10.1055/a-1846-5598
special topic
Aryne Chemistry in Synthesis
Poly(ethylene glycol) Dimethyl Ethers (PEGDME): Efficient and Recyclable Solvents for Aryne-Involved Reactions
Abstract
A variety of aryne reactions are demonstrated in poly(ethylene glycol) dimethyl ethers (PEGDMEs) as solvents without the need of any additive. The reactions proceed efficiently and good yields of the desired products are observed with PEGDME. Further, the advantage of being able to recycle PEG solvents is demonstrated in this work.
Key words
aryne reactions - poly(ethylene glycol) dimethyl ether - metal complexes - recyclable solventSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1846-5598.
- Supporting Information
Publication History
Received: 23 March 2022
Accepted after revision: 09 May 2022
Accepted Manuscript online:
09 May 2022
Article published online:
20 June 2022
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