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Synthesis 2022; 54(23): 5245-5252
DOI: 10.1055/a-1899-5563
DOI: 10.1055/a-1899-5563
paper
Selectfluor-Mediated Oxidative Dehydrogenation of Hydrazines: A Process for the Synthesis of Azo Compounds
We thank the Natural Science Foundation of Shandong Province (ZR2021MB136 and ZR2018BB026), College Students Innovation and Entrepreneurship Training Project of China (202110446051), and the Doctoral Start-Up Scientific Research Foundation of Qufu Normal University.
Abstract
A facile method to synthesize azo compounds from hydrazine derivatives is developed. This represents the unprecedented example of Selectfluor-mediated oxidative dehydrogenation of hydrazine derivatives. The reaction might proceed through N-fluorination and elimination processes. This protocol exhibits key features including simple operation, mild conditions, good functional group tolerance, and high efficiency. Moreover, the advantage is also highlighted by the conversion of a sulfonyl-substituted azo compound to furnish acetanilide in excellent yield under 4 W blue LED irradiation.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1899-5563.
- Supporting Information
Publication History
Received: 09 June 2022
Accepted after revision: 13 July 2022
Accepted Manuscript online:
13 July 2022
Article published online:
01 September 2022
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For transition metal catalysis, see:
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