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Synlett 2023; 34(12): 1492-1496
DOI: 10.1055/a-1979-6123
DOI: 10.1055/a-1979-6123
cluster
Special Issue Honoring Masahiro Murakami’s Contributions to Science
Fused λ5-Phosphinines: Design, Syntheses, and Properties
A part of this work was supported by the Japan Society for the Promotion of Science (JSPS KAKENHI Grant Number JP15K05430, Grant-in-Aid for Scientific Research(C)).
Dedicated to Professor Masahiro Murakami on the occasion of his retirement
Abstract
Synthesis of several heterocycle-fused λ5-phosphinines through intramolecular cyclization is described. The incorporation of a heteroatom affected their photophysical properties through perturbation of the LUMO level, which is in good contrast to the HOMO-based tuning by the C-4 substituent. The C-3-substituent-based property tuning provides a new guide to designing phosphinine-based fluorophores.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1979-6123.
- Supporting Information
Publikationsverlauf
Eingereicht: 24. Oktober 2022
Angenommen: 15. November 2022
Accepted Manuscript online:
15. November 2022
Artikel online veröffentlicht:
01. Dezember 2022
© 2022. Thieme. All rights reserved
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References and Notes
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For reviews, see:
For reviews, see:
For selected syntheses of 6-membered phosphorus heterocycles, see: