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Synthesis 2023; 55(09): 1309-1321
DOI: 10.1055/a-2005-5006
DOI: 10.1055/a-2005-5006
short review
Advances in Exploring Cyclopentadienyl (Cp) Rhodium Catalysts Featuring Diastereotopic or Enantiotopic Cp Faces for Asymmetric C–H Activation
We thank the National Natural Science Foundation of China for financial support (21971263).
Abstract
Chiral cyclopentadienyl rhodium (CpRh) complexes have emerged as a class of powerful catalysts for enantioselective C–H activation reactions. In terms of Cp ligand development, the mainstream is to design chiral ligands with C 2 symmetry in order to avoid the problem of Cp face selectivity during their metalation with rhodium. In recent years, CpRh catalysts with diastereotopic or enantiotopic Cp faces were also revealed and successfully applied in asymmetric C–H activation. These advances are summarized in this short review together with perspectives for their future development.
1 Introduction
2 Cp Ligands with Diastereotopic Cp Faces
3 Cp Ligands with Enantiotopic Cp Faces
4 Conclusion and Outlook
Key words
cyclopentadienyl - rhodium - asymmetric C–H activation - planar chiral - diastereotopic Cp face - enantiotopic Cp face - prochiral CpPublication History
Received: 09 December 2022
Accepted after revision: 02 January 2023
Accepted Manuscript online:
02 January 2023
Article published online:
31 January 2023
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