Electrochemical Synthesis of trans-Olefins from Buta-1,3-dienes and Alkyl Halides

Haoxiang Zhang; Lin Guo; Chao Yang; Wujiong Xia

doi:10.1055/a-2006-1285

Synthesis, Table of Contents

Synthesis 2023; 55(18): 3033-3039
DOI: 10.1055/a-2006-1285

paper

Special Issue Electrochemical Organic Synthesis

Electrochemical Synthesis of trans-Olefins from Buta-1,3-dienes and Alkyl Halides

Haoxiang Zhang

^aState Key Lab of Urban Water Resources and Environment, School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, P. R. of China

,

Lin Guo

^aState Key Lab of Urban Water Resources and Environment, School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, P. R. of China

,

Chao Yang∗

^aState Key Lab of Urban Water Resources and Environment, School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, P. R. of China

,

Wujiong Xia ∗

^aState Key Lab of Urban Water Resources and Environment, School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, P. R. of China

^bSchool of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, P. R. of China

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Abstract

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Abstract

A facile electrochemical alkylation reaction of buta-1,3-diene derivatives with alkyl halides has been developed, generating highly selective trans-olefins as major products. This method exhibits significant advantages, including simple operation, mild conditions, and convenience of scale-up, and provides a novel route for the synthesis of trans-olefins.

Key words

electrochemical reduction - trans-olefins - 1,3-dienes - alkyl halides - radicals

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References

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