Self-Complementary Dimer of Zinc(II) Porphyrins through Coordination with Oxygen Ligands

Dedicated to Professor Guoqiang Lin on the occasion of his 80^th birthday for his great contributions to the development of organic chemistry.

Abstract

Oxygen ligands have been shown to play a critical role in the formation and organization of metalloporphyrin assemblies and natural chlorosomes. In this work, mutually complementary head-to-tail dimers of zinc(II) porphyrins were synthesized through the coordination of zinc with the imide group and 7-oxanorbornene oxygen ligands. UV/Vis absorption and emission, ¹H NMR as well as FT-IR analyses were used to determine the structure. The dimerization association constant K has been determined to be 5.6 M^–1 and 29 M^–1, respectively, by the dilution experiment.

Key words

metalloporphyrins - self-assemble - aggregation - coordination - oxygen ligands - dimerization

Publikationsverlauf

Eingereicht: 23. Februar 2023

Angenommen nach Revision: 24. April 2023

Accepted Manuscript online:
24. April 2023

Artikel online veröffentlicht:
22. Mai 2023

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