Lewis Base/3d Transition-Metal Cooperatively Catalyzed Asymmetric Reactions

Jin Song; Liu-Zhu Gong

doi:10.1055/a-2192-9185

Synlett, Inhaltsverzeichnis

Synlett 2024; 35(14): 1621-1628
DOI: 10.1055/a-2192-9185

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Lewis Base/3d Transition-Metal Cooperatively Catalyzed Asymmetric Reactions

Jin Song

^aInstitutes of Physical Science and Information Technology, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, 230601, P. R. of China

,

Liu-Zhu Gong∗

^bHefei National Research Center for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, P. R. of China

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Abstract

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Abstract

Lewis base/transition-metal cooperatively catalyzed asymmetric transformations have attracted extensive attention as they offer complementary catalytic systems within the realm of cooperative catalysis. Recently, the synergistic use of Lewis bases in combination with earth-abundant 3d metals has emerged as a fascinating prospect, presenting an opportunity to move away from the reliance on noble metals and to explore novel catalytic processes. In this Account, we highlight our recent achievements regarding the chemistry and synthetic utility of isothiourea (ITU) activated C1-ammonium enolates and N-heterocyclic carbene (NHC)-bound homoenolate equivalents in conjunction with 3d transition-metal activated electrophiles. The remarkable success in the stereoselective construction of carbon–carbon and carbon–heteroatom bonds has led to significant contributions to stereodivergent synthesis.

1 Introduction

2 ITU/Copper Cooperative Catalysis

3 NHC/Copper Cooperative Catalysis

4 NHC/Nickel Cooperative Catalysis

5 Conclusion

Key words

Lewis bases - 3d transition metals - cooperative catalysis - asymmetric catalysis - stereodivergent synthesis

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Referenzen

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