Synthesis 2024; 56(21): 3334-3340
DOI: 10.1055/a-2295-8117
paper
Special Issue PSRC-10 (10th Pacific Symposium on Radical Chemistry)

Boosting Sulfonylation Reactions between Vinyl Triflates and Alkenes toward β-Ketosulfones Using Aqueous Sulfurous Acid

Takuji Kawamoto
,
Yuki Takeda
,
Takahiro Kawabata
,
Akio Kamimura
This work was partly supported by the New Energy and Industrial Technology Development Organization (NEDO) (21502091-0) and by the Japan Society for the Promotion of Science (JSPS) Grant-in-Aid for Scientific Research (C) (22K05116).


Abstract

We successfully synthesized trifluoromethylated β-ketosulfones via the reaction of vinyl triflates with alkenes employing aqueous sulfurous acid as an external source of SO2. The PhSSPh/photoinitiated reaction with vinyl triflates that contain electron-deficient groups or halogens did not show any base-related effects, whereas the radical reaction was impeded in the absence of a base in the case of vinyl triflates generated from phenylacetylenes.

Supporting Information



Publication History

Received: 31 January 2024

Accepted after revision: 27 March 2024

Accepted Manuscript online:
27 March 2024

Article published online:
25 April 2024

© 2024. Thieme. All rights reserved

Georg Thieme Verlag KG
Rüdigerstraße 14, 70469 Stuttgart, Germany

 
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