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Synthesis 2024; 56(19): 2963-2972
DOI: 10.1055/a-2307-8257
DOI: 10.1055/a-2307-8257
short review
Transition-Metal-Catalyzed Direct Arylation of Ammonia
This research is supported by the National Natural Science Foundation of China (22171174), the Fundamental Research Funds for the Central Universities (GK202207015, GK202401008), the Natural Science Foundation of Shaanxi Province (2024JC-YBQN-0075), the China Postdoctoral Science Foundation (2023M732165), the Shaanxi Province Postdoctoral Science Foundation (2023BSHYDZZ107), the Young Talent Fund of Association for Science and Technology in Shaanxi, China (20240606).
Abstract
In the past few decades, transition-metal-catalyzed direct amination of aryl halides with ammonia has attracted significant attention from chemists because of its broad substrate scope, good functional group compatibility, and high reaction selectivity. Herein, recent examples of transition-metal-catalyzed syntheses of aniline derivatives starting from aryl halides are reviewed.
1 Introduction
2 Heat-Driven Transition-Metal-Catalyzed Amination of Aryl Electrophiles
2.1 Palladium-Catalyzed Amination
2.2 Copper-Catalyzed Amination
2.3 Nickel-Catalyzed Amination
3 Light-Driven Transition-Metal-Catalyzed Amination of Aryl Electrophiles
4 Conclusion and Outlook
Key words
transition-metals - anilines - aryl electrophiles - amination - cross-coupling - photocatalysis - thermal-driven - catalysisPublication History
Received: 11 March 2024
Accepted after revision: 16 April 2024
Accepted Manuscript online:
16 April 2024
Article published online:
25 April 2024
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