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Synthesis 2024; 56(23): 3630-3636
DOI: 10.1055/a-2385-4181
DOI: 10.1055/a-2385-4181
paper
Facile Synthesis of Silanols via Cesium Carbonate Catalyzed Hydrosilanes with Water
This work was financially supported by the Natural Science Foundation of China (Grant Nos. 21904106, 22174111, and 22174110), the China National Petroleum Corporation (CNPC) Innovation Fund (2020D-5007-0404), and China Postdoctoral Science Foundation (2022M713244).
Abstract
The demand for green and efficient methods for preparing silanols is significant. In this study, we employed inexpensive cesium carbonate as a catalyst to facilitate the hydrolysis of hydrosilanes for silanol production. This approach offers numerous advantages, including mild reaction conditions, broad substrate compatibility, straightforward post-treatment procedures, high yields, and scalability to gram-level synthesis. Our method demonstrated compatibility with diverse organosilanes bearing alkyl, aryl, alkynyl, and heterocyclic substituents, including sterically hindered variants. The significance of these findings extends beyond scientific inquiry, offering practical utility in the synthesis of silanols.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2385-4181.
- Supporting Information
Publication History
Received: 23 June 2024
Accepted after revision: 13 August 2024
Accepted Manuscript online:
13 August 2024
Article published online:
12 September 2024
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