Copper(II)-Catalyzed Esterification
of Arenecarboxylic Acids with Aryl- and Vinyl-Substituted Trimethoxysilanes

Fang Luo; Changduo Pan; Pengcheng Qian; Jiang Cheng

doi:10.1055/s-0029-1218759

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Synthesis 2010(12): 2005-2010
DOI: 10.1055/s-0029-1218759

PAPER

Copper(II)-Catalyzed Esterification of Arenecarboxylic Acids with Aryl- and Vinyl-Substituted Trimethoxysilanes

Fang Luo^a, Changduo Pan^b, Pengcheng Qian^a, Jiang Cheng*^a
^a College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325000, P. R. of China
Fax: +86(577)56998939; e-Mail: jiangcheng@wzu.edu.cn;
^b Wenzhou Institute of Industry & Science, Wenzhou 325000, P. R. of China

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Publication History

Received 24 February 2010
Publication Date:
29 April 2010 (online)

Abstract
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Abstract

In this paper, the copper(II)-catalyzed esterification reaction of arenecarboxylic acids with aryl- or vinyl-substituted trimethoxysilanes is described. A series of aryltrimethoxysilanes and arenecarboxylic acids worked well under this procedure, affording aryl benzoate derivatives in moderate to good yields. Notably, trimethoxy(vinyl)silanes also worked well under this procedure giving a facile and versatile method to access vinyl benzoate derivatives.

Key words

copper(II) catalyzed - trimethoxysilanes - carboxylic acids - esters - silver(I) fluoride

Supporting Information

References

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Supplementary Material

Supporting Information