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Synthesis 2010(14): 2463-2467  
DOI: 10.1055/s-0029-1218786
PAPER
© Georg Thieme Verlag Stuttgart ˙ New York

Rapid and Convenient One-Pot Method for the Preparation of Alkali Metal Phosphinodiselenoates

Alexander V. Artem’ev, Svetlana F. Malysheva, Nina K. Gusarova, Boris A. Trofimov*
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky St., 664033 Irkutsk, Russian Federation
Fax: +7(3952)419346; e-Mail: boris_trofimov@irioch.irk.ru;
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Publication History

Received 19 March 2010
Publication Date:
12 May 2010 (online)

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Abstract

Alkali metal phosphinodiselenoates, R2PSe2M (R = aralkyl, hetaralkyl, Ph; M = Li, Na, K, Rb, Cs), were synthesized in high yields (up to 98%) by a three-component reaction of a secondary phosphine, elemental selenium, and an alkali metal hydroxide under mild conditions (ethanol, room temperature, 5 min).

Key words

phosphorus - selenium - alkali metals - three-component reactions - phosphinodiselenoates - alkali metal salts

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