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Synlett 2010(12): 1819-1824
DOI: 10.1055/s-0030-1258125
DOI: 10.1055/s-0030-1258125
LETTER
© Georg Thieme Verlag
Stuttgart ˙ New York
Palladium-Catalyzed N-Arylation of Bis(ortho-substituted aryl)amines: an Efficient Method for Preparing Sterically Congested Triarylamines
Further Information
Publication History
Received
15 May 2010
Publication Date:
30 June 2010 (online)
Abstract
Bis(ortho-substituted aryl)amines were arylated on the nitrogen atom with various haloarenes in high yields using the palladium catalyst, which was generated from palladium(II) acetate and tri(tert-butyl)phosphine.
Key words
amination - arylation - cross-coupling - homogeneous catalysis - palladium
- Supporting Information for this article is available online:
- Supporting Information