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Synlett 2011(3): 402-404
DOI: 10.1055/s-0030-1259314
DOI: 10.1055/s-0030-1259314
LETTER
© Georg Thieme Verlag
Stuttgart ˙ New YorkCatalytic Enantioselective Synthesis of 3-Substituted Benzosultams via Corey-Bakshi-Shibata Reduction of Cyclic N-Sulfonylimines
Weitere Informationen
Received
23 November 2010
Publikationsdatum:
13. Januar 2011 (online)
Publikationsverlauf
Publikationsdatum:
13. Januar 2011 (online)
Abstract
The catalytic asymmetric synthesis of 3-substituted benzo-fused sultams employing the Corey-Bakshi-Shibata reduction with catecholborane of the corresponding cyclic N-sulfonylimines is reported. Good to excellent yields (74-95%) and enantiomeric excesses (69-94%) are obtained.
Key words
asymmetric synthesis - imine - reduction - catalysis - sulfonamide
- Supporting Information for this article is available online:
- Supporting Information
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References and Notes
For experimental details, see Supporting Information.