Synthesis of 1-Pentafluorosulfanyl-1,3-Dienes

Abstract

A series of pentafluorosulfanyl-substituted dienes has been synthesized from 3-pentafluorosulfanyl-prop-2-enal employing either Grignard reactions with subsequent dehydration or by ­oxidation of 1-pentafluorosulfanyl-alk-1-en-3-ols to the corresponding ketones and subsequent Wittig-type olefinations.

Key words

dehydration - 1,3-dienes - Grignard reaction - pentafluorosulfanyl group - oxidation - Wittig reaction

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