Abstract
This account summarizes recent work by us and others on the development
of ligands for the separation of actinides from lanthanides contained
in nuclear waste streams in the context of a future European strategy
for nuclear waste management. The current status of actinide/lanthanide
separations worldwide is briefly discussed, and the synthesis, development,
and testing of different classes of heterocyclic soft N - and S -donor
ligands in Europe over the last 20 years is presented. This work
has led to the current benchmark ligand that displays many of the
desirable qualities for industrial use. The improvement of radiolytic
stability through ligand design is also discussed.
1 Introduction and Background
2 Dithiophosphinic Acids
3 2,2′:6′,2′′-Terpyridine
(TERPY) and Related Ligands
4 2,4,6-Tri-2-pyridyl-1,3,5-triazine (TPTZ) and Related Ligands
5 2,6-Bis(benzoxazol-2-yl)-4-dodecyloxypyridine (BODO) and Related
Ligands
6 Podand Ligands
7 2,6-Bis(1,2,4-triazin-3-yl)pyridine (BTP) and Related Ligands
8 6,6′-Bis(1,2,4-triazin-3-yl)-2,2′-bipyridine
(BTBP) and Related Ligands
9 Improving Radiolytic Stability through Ligand Design
10 Conclusion and Outlook
Key words
heterocycles - ligands - actinides - solvent
extraction - lanthanides
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