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Synthesis 2013; 45(4): 421-437
DOI: 10.1055/s-0032-1316846
DOI: 10.1055/s-0032-1316846
review
Multimetallic Schiff Base Complexes as Cooperative Asymmetric Catalysts
Further Information
Publication History
Received: 30 November 2012
Accepted after revision: 19 December 2012
Publication Date:
14 January 2013 (online)
Abstract
Multimetallic salen and related Schiff base complexes designed for cooperative asymmetric catalysis are introduced. First, studies to enhance the cooperative function of two distinct metal–salen units using covalently linked metal–salen complexes, supramolecular bimetallic salens as well as μ-oxo-bridged metal salens are described. Then, studies to design dinuclear Schiff base catalysts that exhibit unique intramolecular cooperative functions of two distinct metals are discussed in detail.
1 Introduction
2 Covalently Linked Metal Salens
3 Supramolecular Bimetallic Salens
4 μ-Oxo-Bridged Metal Salens
5 Heterodinuclear Schiff Base Complexes
6 Homodinuclear Schiff Base Complexes
7 Summary
-
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Reviews:
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For examples of polymer-supported metal–salen complexes to enhance bimolecular cooperative function, see reviews:
For selected representative examples, see:
The synthetic utility of the μ-oxo dimeric Al-L1 catalyst was demonstrated by Jacobsen and co-workers in many enantioselective reactions and catalytic asymmetric tota syntheses of natural products. For representative examples, see:
North and co-workers also reported the utility of μ-oxo dimeric Al-L1 catalyst as the intramolecular cooperative catalyst in epoxide ring opening reaction with CO2: