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Synthesis 2013; 45(9): 1121-1159
DOI: 10.1055/s-0032-1316869
DOI: 10.1055/s-0032-1316869
review
Claisen Rearrangement of Aliphatic Allyl Vinyl Ethers from 1912 to 2012: 100 Years of Electrophilic Catalysis
Further Information
Publication History
Received: 06 January 2013
Accepted after revision: 12 February 2013
Publication Date:
17 April 2013 (online)
Abstract
This review summarizes, from a personal perspective, the development of catalytic asymmetric Claisen rearrangements from 1912 to 2012.
1 Introduction
2 Gosteli–Claisen Rearrangement
3 Claisen Rearrangement Using Stable Enols: Kojic Acid and Diosphenols
4 The Early Years: Catalysis by Brønsted Acids
5 Lewis Acid Mediated Claisen Rearrangements: The Aluminum Age
6 Catalysis by Precious Metals
7 Catalysis by σ-Lewis Acids
8 Catalysis by Achiral Organocatalysts
9 Catalytic Asymmetric Claisen Rearrangements
10 Conclusion
-
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