Palladium-Catalyzed Domino Carbopalladation/C–H Activation for the Synthesis of Tetrasubstituted Alkenes Bearing Five- and Seven-Membered Rings

Lutz F. Tietze; Tim Hungerland; Christian Depken; Christian Maaß; Dietmar Stalke

doi:10.1055/s-0032-1317325

Synlett, Inhaltsverzeichnis

Synlett 2012; 23(17): 2516-2520
DOI: 10.1055/s-0032-1317325

letter

Palladium-Catalyzed Domino Carbopalladation/C–H Activation for the Synthesis of Tetrasubstituted Alkenes Bearing Five- and Seven-Membered Rings

Lutz F. Tietze*

^aInstitute of Organic and Biomolecular Chemistry of the Georg-August-University Göttingen, Tammannstr. 2, 37077 Göttingen, Germany Fax: +49(551)399476 eMail: ltietze@gwdg.de

,

Tim Hungerland

^aInstitute of Organic and Biomolecular Chemistry of the Georg-August-University Göttingen, Tammannstr. 2, 37077 Göttingen, Germany Fax: +49(551)399476 eMail: ltietze@gwdg.de

,

Christian Depken

^aInstitute of Organic and Biomolecular Chemistry of the Georg-August-University Göttingen, Tammannstr. 2, 37077 Göttingen, Germany Fax: +49(551)399476 eMail: ltietze@gwdg.de

,

Christian Maaß

^bInstitute of Inorganic Chemistry of the Georg-August-University Göttingen, Tammannstr. 4, 37077 Göttingen, Germany

,

Dietmar Stalke

^bInstitute of Inorganic Chemistry of the Georg-August-University Göttingen, Tammannstr. 4, 37077 Göttingen, Germany

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Abstract

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Abstract

A Pd-catalyzed domino carbopalladation/C–H-activation reaction of phenoxyphenyl-substituted propargylic alcohols was used for the synthesis of tetrasubstituted alkenes bearing either a dihydroindene or benzo[7]annulene motif. These compounds are of interest for the construction of molecular switches and motors.

Key words

palladium - domino reaction - C–H activation - tetrasubstituted alkenes - catalysis

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Referenzen

References and Notes

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10 CCDC-881349 (7d), CCDC-881350 (8b), and CCDC-881351 (10) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via the internet from The Cambridge Crystallographic Data Centre (www.ccdc.cam.ac.uk/data_request/cif).
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