A Concise Synthesis of 4-Vinylphencyphos

Maarten W. van der Meijden; Klaus Wurst; Richard M. Kellogg

doi:10.1055/s-0032-1318453

Synlett, Table of Contents

Synlett 2013; 24(6): 770-772
DOI: 10.1055/s-0032-1318453

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A Concise Synthesis of 4-Vinylphencyphos

Maarten W. van der Meijden

^aSyncom BV, Kadijk 3, 9747 AT Groningen, The Netherlands Fax: +31(50)5757399 Email: r.m.kellogg@syncom.nl

,

Klaus Wurst

^bInstitut für Allgemeine Anorganische und Theoretische Chemie, Universität Innsbruck, Innrain 80/82, 6020 Innsbruck, Austria

,

Richard M. Kellogg*

^aSyncom BV, Kadijk 3, 9747 AT Groningen, The Netherlands Fax: +31(50)5757399 Email: r.m.kellogg@syncom.nl

› Author Affiliations

Abstract

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Abstract

A fast and clean procedure has been found to prepare the 4-vinyl derivative of enantiomerically pure 2-hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphinan-2-oxide, commonly known as phencyphos. This cyclic phosphoric acid is a popular acidic resolving agent. Functionalization opens a route to attachment to surfaces.

Key words

Hiyama coupling - resolving agent - phosphoric acid - chiral

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References

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