Ligand-Assisted Copper-Catalyzed Oxidative Cross-Coupling of Simple 
Phenols with Formamides for the Synthesis of Carbamates

Nagireddy Veera Reddy; Gadde Sathish Kumar; Pailla Santhosh Kumar; M. Lakshmi Kantam; Kallu Rajender Reddy

doi:10.1055/s-0034-1378519

Synlett, Inhaltsverzeichnis

Synlett 2014; 25(15): 2133-2138
DOI: 10.1055/s-0034-1378519

letter

Ligand-Assisted Copper-Catalyzed Oxidative Cross-Coupling of Simple Phenols with Formamides for the Synthesis of Carbamates

Nagireddy Veera Reddy

Inorganic and Physical Chemistry Division, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad – 500 607, India Fax: +91(40)27160921 eMail: rajender@iict.res.in eMail: rajenderkallu@yahoo.com

,

Gadde Sathish Kumar

Inorganic and Physical Chemistry Division, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad – 500 607, India Fax: +91(40)27160921 eMail: rajender@iict.res.in eMail: rajenderkallu@yahoo.com

,

Pailla Santhosh Kumar

Inorganic and Physical Chemistry Division, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad – 500 607, India Fax: +91(40)27160921 eMail: rajender@iict.res.in eMail: rajenderkallu@yahoo.com

,

M. Lakshmi Kantam

Inorganic and Physical Chemistry Division, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad – 500 607, India Fax: +91(40)27160921 eMail: rajender@iict.res.in eMail: rajenderkallu@yahoo.com

,

Kallu Rajender Reddy*

Inorganic and Physical Chemistry Division, CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad – 500 607, India Fax: +91(40)27160921 eMail: rajender@iict.res.in eMail: rajenderkallu@yahoo.com

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Abstract

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Abstract

An oxidative approach for the synthesis of phenyl carbamates has been achieved by ligand-assisted copper-catalyzed cross-dehydrogenative coupling (CDC) of phenols with formamides. The direct coupling of simple phenols with mono- and dialkyl formamides provides carbamate products in moderate to good yields under mild reaction conditions.

Key words

oxidation - formamide - carbamate - copper acetate - coupling reaction

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References and Notes

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Zusatzmaterial

Supporting Information