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Synthesis 2015; 47(22): 3460-3466
DOI: 10.1055/s-0034-1378810
DOI: 10.1055/s-0034-1378810
paper
Silver-Catalyzed Tandem Trifluoromethylation and Cyclization of Aryl Isonitriles with the Langlois Reagent
Further Information
Publication History
Received: 19 May 2015
Accepted after revision: 11 June 2015
Publication Date:
12 August 2015 (online)
Abstract
A mild and efficient procedure for the silver-catalyzed tandem trifluoromethylation and cyclization of aryl isonitriles with the Langlois reagent (sodium triflinate) is developed. A series of trifluoromethylated phenanthridines is prepared in moderate to good yields from a cheap and stable trifluoromethyl source.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1378810.
- Supporting Information
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For selected examples, see: