A Facile and Selective Procedure for Oxidation of Hydroquinones using Silica Gel Supported Catalytic Cerium(IV) Ammonium Nitrate

Mohammed Hashmat Ali; Andrea Welker; Crystal York

doi:10.1055/s-0034-1380439

Synthesis, Inhaltsverzeichnis

Synthesis 2015; 47(20): 3207-3211
DOI: 10.1055/s-0034-1380439

paper

A Facile and Selective Procedure for Oxidation of Hydroquinones using Silica Gel Supported Catalytic Cerium(IV) Ammonium Nitrate

Mohammed Hashmat Ali*

Department of Chemistry, Southeast Missouri State University, One University Plaza, Cape Girardeau, MO 63701, USA eMail: mhali@semo.edu

,

Andrea Welker

Department of Chemistry, Southeast Missouri State University, One University Plaza, Cape Girardeau, MO 63701, USA eMail: mhali@semo.edu

,

Crystal York

Department of Chemistry, Southeast Missouri State University, One University Plaza, Cape Girardeau, MO 63701, USA eMail: mhali@semo.edu

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Abstract

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Abstract

A new procedure for oxidation of hydroquinones to quinones using a silica gel supported cerium(IV) ammonium nitrate-NaBrO₃ reagent has been developed. This simple, easy to prepare and use, heterogeneous reagent is highly selective towards oxidation of 1,4-dihydroxybenzenes and produces high yields of quinones. Waste generated by using this procedure is minimal.

Key words

heterogeneous - solid support - oxidation - hydroquinone - quinone

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Referenzen

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