Ligand-Free Palladium-Catalyzed Hydroxycarbonylation of Aryl Halides under Ambient Conditions: Synthesis of Aromatic Carboxylic Acids and Aromatic Esters

Wei Han; Fengli Jin; Qing Zhou

doi:10.1055/s-0034-1380497

Synthesis, Inhaltsverzeichnis

Synthesis 2015; 47(13): 1861-1868
DOI: 10.1055/s-0034-1380497

paper

Ligand-Free Palladium-Catalyzed Hydroxycarbonylation of Aryl Halides under Ambient Conditions: Synthesis of Aromatic Carboxylic Acids and Aromatic Esters

Wei Han*

^aJiangsu Key Laboratory of Biofunctional Materials, Key Laboratory of Applied Photochemistry, School of Chemistry and Materials Science, Nanjing Normal University, Wenyuan Road No. 1, Nanjing 210023, P. R. of China

^bJiangsu Collaborative Innovation Center of Biomedical Functional Materials, Nanjing 210023, P. R. of China eMail: hanwei@njnu.edu.cn

,

Fengli Jin

^aJiangsu Key Laboratory of Biofunctional Materials, Key Laboratory of Applied Photochemistry, School of Chemistry and Materials Science, Nanjing Normal University, Wenyuan Road No. 1, Nanjing 210023, P. R. of China

,

Qing Zhou

^aJiangsu Key Laboratory of Biofunctional Materials, Key Laboratory of Applied Photochemistry, School of Chemistry and Materials Science, Nanjing Normal University, Wenyuan Road No. 1, Nanjing 210023, P. R. of China

› Institutsangaben

Abstract

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Abstract

Aryl halides were readily converted into their corresponding aromatic carboxylic acids in high yields with high selectivity by ligand-free palladium-catalyzed hydroxycarbonylation at room temperature and atmospheric pressure. The new method is operationally simple and scalable. In addition, aromatic esters were easily synthesized through one-pot hydroxycarbonylation/alkylation with alkyl halides.

Key words

aryl halides - carbonylation - carboxylic acids - hydroxycarbonylation - palladium

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Referenzen

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