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Synthesis 2016; 48(13): 2009-2025
DOI: 10.1055/s-0035-1560440
DOI: 10.1055/s-0035-1560440
short review
Photochemical Synthesis of Azaheterocycles
Further Information
Publication History
Received: 24 February 2016
Accepted after revision: 03 March 2016
Publication Date:
12 April 2016 (online)
Abstract
Synthetic organic photochemistry is a field that continues to offer unique routes to organic structures not typically accessed from thermal reactions. In this review, the photochemical synthesis of five-, six-, seven-, and eight-membered-ring azaheterocycles, as well as some aza-macrocycles, is discussed. The discussion will focus on methods where heterocycle formation occurs during or as a result of a photochemical event. Reaction mechanisms will be discussed also, as these provide a rationale for understanding the synthetic results.
1 Introduction
2 Five-Membered Rings
2.1 Cyclization Reactions
2.2 Cycloadditions
2.3 From Aromatic and Vinyl Azides
2.4 earrangements
2.5 Other Individual Methods
3 Six-Membered Rings
3.1 Cyclization Reactions
3.2 Isocyanide Insertions
3.3 Cycloadditions
4 Seven-Membered Rings and Larger
5 Conclusion
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