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Synthesis 2016; 48(01): 85-96
DOI: 10.1055/s-0035-1560481
DOI: 10.1055/s-0035-1560481
paper
Synthesis of Isoselenocyanates
Further Information
Publication History
Received: 03 June 2015
Accepted after revision: 25 August 2015
Publication Date:
29 October 2015 (online)
Abstract
Isoselenocyanates were synthesized by two methods under phase-transfer conditions (50% aq NaOH, CH2Cl2, Aliquat 336); the first started from isocyanides and selenium and gave isoselenocyanates in 61–89% yields, while the second started from amines and used chloroform and selenium, by applying sequentially the Hofmann isonitrile synthesis and the addition of selenium, in 4–70% yields.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1560481. Spectra of isocyanides 3a–l and isoselenocyanates 4a–l are provided.
- Supporting Information
-
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