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Synlett 2016; 27(03): 395-398
DOI: 10.1055/s-0035-1560527
DOI: 10.1055/s-0035-1560527
letter
One-Pot Palladium(II)-Catalyzed Synthesis of Fluorenones via Decarboxylative Cyclization
Autor*innen
Weitere Informationen
Publikationsverlauf
Received: 31. August 2015
Accepted after revision: 05. Oktober 2015
Publikationsdatum:
19. November 2015 (online)
Abstract
A one-pot palladium-catalyzed synthesis of fluoronones via decarboxylative cyclization is reported. This protocol offers good yields and tolerates a broad range of functional groups. Based on the extensive experimental data, we propose a plausible decarboxylative insertion mechanism.
Key words
palladium-catalyzed - decarboxylative insertion - C–C cleavage - control experiment - mechanismSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1560527.
- Supporting Information (PDF) (opens in new window)
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