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Synthesis 2016; 48(05): 751-760
DOI: 10.1055/s-0035-1561298
DOI: 10.1055/s-0035-1561298
paper
Synthesis of Allenylphosphonates through Cu(I)-Catalyzed Coupling of Terminal Alkynes with Diazophosphonates
Further Information
Publication History
Received: 15 October 2015
Accepted after revision: 26 November 2015
Publication Date:
04 January 2016 (online)
Abstract
Through the Cu(I)-catalyzed coupling of diazophosphonates with terminal alkynes, an efficient method for the synthesis of allenylphosphonates has been developed. Simple and inexpensive CuI is used as the catalyst and the reaction is conducted under mild conditions.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561298.
- Supporting Information
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For reviews on allenes, see:
For reviews, see: