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Synthesis 2016; 48(11): 1597-1606
DOI: 10.1055/s-0035-1561586
DOI: 10.1055/s-0035-1561586
short review
Recent Advances in Meerwein Arylation Chemistry
Weitere Informationen
Publikationsverlauf
Received: 25. Februar 2016
Accepted after revision: 29. Februar 2016
Publikationsdatum:
31. März 2016 (online)
Abstract
The Meerwein arylation has recently received much attention and a variety of new variants have been developed. Advances include new sources for aryl radicals, new radical scavengers, as well as improved reaction conditions. This short review summarizes important developments that make this radical-type reaction an even more powerful tool for the diverse functionalization of alkenes.
1 Introduction
2 Meerwein Arylations
2.1 Carboarylation
2.2 Carboamination
2.3 Carbooxygenation
2.4 Carbothiolation
2.5 Carbofluorination
3 Summary
-
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For review articles, see:
For organotin-mediated atom-transfer reactions, see:
For atom transfer with alternative reagents, see:
For atom transfer under electrochemical and photochemical conditions, see:
For variety of suitable alkenes in CuCl2-mediated reactions, see:
For a carbooxygenation via path A (Scheme 1), see:
For rhodium-catalyzed carbothiolations of alkynes, see:
For alternative sulfur-centered radical scavengers, see:
For related alkyl- and acyl-carbofluorinations, see:
For reviews on radical fluorine transfer, see:
Selectfluor [1-chloromethyl-4-fluoro-1,4-diazabicyclo[2.2.2] octane bis(tetrafluoroborate)]: