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Synthesis 2017; 49(23): 5149-5158
DOI: 10.1055/s-0036-1588513
DOI: 10.1055/s-0036-1588513
paper
Palladium-Catalyzed Copper-Free Sonogashira Coupling of 2-Bromoarylcarbonyls: Synthesis of Isobenzofurans via One-Pot Reductive Cyclization
Authors
We are grateful to the Council of Scientific and Industrial Research (CSIR), New Delhi, for the financial support [Sanction No. 02(0262)/16/EMR-11].
Further Information
Publication History
Received: 27 June 2017
Accepted after revision: 29 June 2017
Publication Date:
02 August 2017 (online)
Abstract
Palladium-catalyzed copper-free Sonogashira coupling of 2-bromocarbonyls is presented. This method afforded the 2-alkynylaryl carbonyls, useful synthons for the accomplishment of many carbocyclic and heterocyclic motifs. Significantly, the strategy was extended to the one-pot synthesis of isobenzofurans via reduction followed by intramolecular 5-exo-dig cyclization.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1588513.
- Supporting Information (PDF) (opens in new window)
- CIF File (ZIP) (opens in new window)
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