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Synthesis 2019; 51(02): 334-358
DOI: 10.1055/s-0037-1609635
DOI: 10.1055/s-0037-1609635
review
Cu(III)-Mediated Aerobic Oxidations
Financial support was provided by the Natural Sciences and Engineering Council of Canada (NSERC, J.-P.L.). K.V.N.E acknowledges NSERC for a PDF scholarship.Further Information
Publication History
Received: 19 August 2018
Accepted after revision: 07 October 2018
Publication Date:
03 December 2018 (online)
Abstract
CuIII species have been invoked in many copper-catalyzed transformations including cross-coupling reactions and oxidation reactions. In this review, we will discuss seminal discoveries that have advanced our understanding of the CuI/CuIII redox cycle in the context of C–C and C–heteroatom aerobic cross-coupling reactions, as well as C–H oxidation reactions mediated by CuIII–dioxygen adducts.
1 General Introduction
2 Early Examples of CuIII Complexes
3 Aerobic CuIII-Mediated Carbon–Heteroatom Bond-Forming Reactions
4 Aerobic CuIII-Mediated Carbon–Carbon Bond-Forming Reactions
5 Bioinorganic Studies of CuIII Complexes from CuI and O2
5.1 O2 Activation
5.2 Biomimetic CuIII Complexes from CuI and Dioxygen
5.2.1 Type-3 Copper Enzymes and Dinuclear Cu Model Complexes
5.2.2 Particulate Methane Monooxygenase and Di- and Trinuclear Cu Model Complexes
5.2.3 Dopamine–β-Monooxygenase and Mononuclear Cu Model Complexes
6 Conclusion
-
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