Heterogeneous Iron-Catalyzed Hydrogenation of Nitroarenes under Water-Gas Shift Reaction Conditions

Pavel Ryabchuk; Kathrin Junge; Matthias Beller

doi:10.1055/s-0037-1610196

Synthesis, Table of Contents

Synthesis 2018; 50(22): 4369-4376
DOI: 10.1055/s-0037-1610196

paper

Heterogeneous Iron-Catalyzed Hydrogenation of Nitroarenes under Water-Gas Shift Reaction Conditions

Pavel Ryabchuk

Leibniz-Institut für Katalyse e.V., Albert Einstein Str. 29a, 18059 Rostock, Germany Email: matthias.beller@catalysis.de

,

Kathrin Junge

Leibniz-Institut für Katalyse e.V., Albert Einstein Str. 29a, 18059 Rostock, Germany Email: matthias.beller@catalysis.de

,

Matthias Beller*

Leibniz-Institut für Katalyse e.V., Albert Einstein Str. 29a, 18059 Rostock, Germany Email: matthias.beller@catalysis.de

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Abstract

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This article is dedicated in honor of Professor Scott Denmark’s 65^th birthday.

Published as part of the Special Section dedicated to Scott E. Denmark on the occasion of his 65^th birthday

Abstract

Reduction of various nitroarenes in the presence of heterogeneous iron oxide-based catalyst Fe₂O₃/NGr@C under water-gas shift reaction (WGSR) conditions has been demonstrated. The catalytic material is prepared in a straightforward manner via deposition/pyrolysis of iron-phenanthroline complex on carbon support. It shows high chemoselectivity towards the reduction of nitroarenes in the presence of other reducible and/or poisoning-capable functional groups. Hydrogenation is achieved using CO/H₂O as a hydrogen source. Furthermore, it is demonstrated that the presence of triethylamine additive has a significant positive effect on the rate of reduction.

Key words

reduction - water-gas shift reaction - WGSR - heterogeneous catalysis - iron - nanoparticles - nitroarenes - hydrogenation

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References

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