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Synthesis 2019; 51(02): 557-563
DOI: 10.1055/s-0037-1610831
DOI: 10.1055/s-0037-1610831
paper
Synthesis and Optical Resolution of 3,3,3′,3′-Tetramethyl-1,1′-spirobiindane-7,7′-diol
We appreciate the National Natural Science Foundation of China (21572200) and the Fundamental Research Funds for the Central Universities (2017QNA3013) for financial support.
Further Information
Publication History
Received: 28 May 2018
Accepted after revision: 30 July 2018
Publication Date:
04 September 2018 (online)
Abstract
A novel chiral C2-symmetric spiro diol, 3,3,3′,3′-tetramethyl-1,1′-spirobiindane-7,7′-diol (TMSIOL), was conveniently prepared via practical seven-step route from Bisphenol A in 45.1% overall yield. l-Menthyl chloroformate is used as optical resolving agent for the separation of the two enantiomers of TMSIOL.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1610831.
- Supporting Information
-
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For selected examples by other groups, see:
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