Ruthenium-Catalyzed Selective Reduction of Carboxylic Esters and Carboxamides

Yongyun Zhou; Ruhima Khan; Baomin Fan; Lijin Xu

doi:10.1055/s-0037-1611524

Synthesis, Inhaltsverzeichnis

Synthesis 2019; 51(12): 2491-2505
DOI: 10.1055/s-0037-1611524

special topic

Ruthenium-Catalyzed Selective Reduction of Carboxylic Esters and Carboxamides

Yongyun Zhou

^aYMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University, Kunming 650504, P. R. of China eMail: adams.bmf@hotmail.com

,

Ruhima Khan

^aYMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University, Kunming 650504, P. R. of China eMail: adams.bmf@hotmail.com

,

Baomin Fan *

^aYMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University, Kunming 650504, P. R. of China eMail: adams.bmf@hotmail.com

,

Lijin Xu*

^bDepartment of Chemistry, Renmin University of China, Beijing 100872, P. R. of China eMail: 20050062@ruc.edu.cn

› Institutsangaben

Abstract

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Published as part of the Special Topic Ruthenium in Organic Synthesis

Abstract

Amines and alcohols are important classes of building blocks in organic synthesis. The synthesis of these compounds has been a topic of interest. A straightforward method for their synthesis is the reduction of esters and amides to alcohols and amines, respectively. Various transition-metal catalysts have been developed for the homogeneous hydrogenation of esters and amides to alcohols and amines. In this review, an overview of the ruthenium-catalyzed selective hydrogenation of esters and amides is provided.

1 General Introduction

2 Ru-Catalyzed Reduction of Esters

3 Ru-Catalyzed Selective Reduction of Amides

4 Conclusions

Key words

esters - amides - hydrogenation - ruthenium - amines - alcohols

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Referenzen

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