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Synthesis 2020; 52(13): 1903-1914
DOI: 10.1055/s-0039-1690091
DOI: 10.1055/s-0039-1690091
paper
Nickel-Catalysed Allylboration of Aldehydes
Authors
This work was supported by the University of Sheffield and the Engineering and Physical Sciences Research Council (EPSRC).
Further Information
Publication History
Received: 13 January 2020
Accepted after revision: 04 March 2020
Publication Date:
18 March 2020 (online)
Abstract
A nickel catalyst for the allylboration of aldehydes is reported, facilitating the preparation of homoallylic alcohols in high diastereoselectivity. The observed diastereoselectivities and NMR experiments suggest that allylation occurs through a well-defined six-membered transition state, with nickel acting as a Lewis acid.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690091.
- Supporting Information (PDF)
-
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For selected reviews on allylboration, see: