Base-Promoted Direct Synthesis of Sulfinates from N-Sulfonyl­hydrazones under Metal-Free Conditions

Yuan-Zhao Ji; Qin-Xi Wu; Hui-Jing Li; Dong-Hui Luo; Yan-Chao Wu

doi:10.1055/s-0039-1690754

Synthesis, Inhaltsverzeichnis

Synthesis 2020; 52(05): 755-762
DOI: 10.1055/s-0039-1690754

paper

Base-Promoted Direct Synthesis of Sulfinates from N-Sulfonylhydrazones under Metal-Free Conditions

Yuan-Zhao Ji

^aSchool of Marine Science and Technology, Harbin Institute of Technology, 2 Wenhuaxi Road, Weihai 264209, P. R. of China

,

Qin-Xi Wu

^aSchool of Marine Science and Technology, Harbin Institute of Technology, 2 Wenhuaxi Road, Weihai 264209, P. R. of China

,

Hui-Jing Li∗

^aSchool of Marine Science and Technology, Harbin Institute of Technology, 2 Wenhuaxi Road, Weihai 264209, P. R. of China

^bWeihai Institute of Marine Biomedical Industrial Technology, Wendeng District, Weihai 264400, P. R. of China eMail: lihuijing@iccas.ac.cn eMail: ycwu@iccas.ac.cn

,

Dong-Hui Luo

^aSchool of Marine Science and Technology, Harbin Institute of Technology, 2 Wenhuaxi Road, Weihai 264209, P. R. of China

,

Yan-Chao Wu ∗

^aSchool of Marine Science and Technology, Harbin Institute of Technology, 2 Wenhuaxi Road, Weihai 264209, P. R. of China

^bWeihai Institute of Marine Biomedical Industrial Technology, Wendeng District, Weihai 264400, P. R. of China eMail: lihuijing@iccas.ac.cn eMail: ycwu@iccas.ac.cn

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Abstract

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Abstract

A base-promoted direct synthesis of sulfinates from N-sulfonylhydrazones is described. Various N-sulfonylhydrazones, derived from aldehydes and ketones, are converted into the corresponding sulfinates in moderate to good yields. This protocol possesses many advantages such as readily available and stable starting materials, broad substrate scope, and metal-free reaction conditions.

Key words

sulfinates - hydrazones - DIPEA - carbonyl compounds - sulfonylhydrazines

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Supporting Information

Base-Promoted Direct Synthesis of Sulfinates from N-Sulfonyl­hydrazones under Metal-Free Conditions

Base-Promoted Direct Synthesis of Sulfinates from N-Sulfonylhydrazones under Metal-Free Conditions