Catalyst- and Solvent-Free Synthesis of α-Amino Polyfluoroalkylphosphonates from Bis(fluoroalkyl) Phosphonates and Aldimines

Svetlana N. Arbuzova; Nina K. Gusarova; Tatyana I. Kazantseva; Svetlana I. Verkhoturova; Sergey V. Zinchenko; Nikita A. Kolyvanov; Boris A. Trofimov

doi:10.1055/s-0039-1691599

Synthesis, Inhaltsverzeichnis

Synthesis 2020; 52(10): 1531-1540
DOI: 10.1055/s-0039-1691599

paper

Catalyst- and Solvent-Free Synthesis of α-Amino Polyfluoroalkylphosphonates from Bis(fluoroalkyl) Phosphonates and Aldimines

Svetlana N. Arbuzova

,

Nina K. Gusarova

,

Tatyana I. Kazantseva

,

Svetlana I. Verkhoturova

,

Sergey V. Zinchenko

,

Nikita A. Kolyvanov

,

Boris A. Trofimov∗

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation eMail: boris_trofimov@irioch.irk.ru

› Institutsangaben

Abstract

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Abstract

The catalyst- and solvent-free reaction between bis(fluoroalkyl) phosphonates and aldimines occurs under mild conditions (20–22 °C, 0.25–4 h) to afford a new family of α-amino polyfluoroalkylphosphonates in up to quantitative yields.

Key words

bis(fluoroalkyl) phosphonates - aldimines - catalyst-free - solvent-free - α-amino polyfluoroalkylphosphonates

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References

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