Recent Advances in Metal-Catalyzed, Electrochemical Coupling Reactions of sp2 Halides/Boronic Acids and sp3 Centers

Zachary J. Gale-Day

doi:10.1055/s-0040-1706085

Synthesis, Table of Contents

Synthesis 2021; 53(05): 879-888
DOI: 10.1055/s-0040-1706085

short review

Recent Advances in Metal-Catalyzed, Electrochemical Coupling Reactions of sp² Halides/Boronic Acids and sp³ Centers

Zachary J. Gale-Day ∗

Abstract

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Abstract

Traditionally, metal-catalyzed cross-coupling reactions rely on stable but expensive metals, such as palladium. However, the recent development of synthetic organic electrochemistry allows for in situ redox manipulations, expanding the use of cheaper, abundant and sustainable metals, such as nickel and copper as efficient cross-coupling catalysts. This short review covers the recent advances in metal-catalyzed electrochemical coupling reactions, with a focus on reactions of sp² electrophiles and nucleophiles with sp³ coupling partners to form both C–C and C–heteroatom bonds.

1 Introduction

2 Nickel-Catalyzed C–C sp²–sp³ Coupling Reactions

3 Coupling of Aryl Groups with Heteroatomic Nuclei

4 Conclusion

Key words

electrochemistry - nickel - copper - reduction - cross-coupling - sp²–sp³

Full Text

References

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