Carbonyl-Photoredox/Metal Dual Catalysis: Applications in Organic Synthesis

Abstract

Photoredox/metal dual catalysis is a versatile tandem methodology to construct carbon–carbon and carbon–heteroatom bonds. The focus of this short review is the application of this technology to C(sp³)–C(sp³), C(sp³)–C(sp²), C(sp²)–C(sp²), C(sp²)–O, and C(sp³)–O bond formation induced by readily available and inexpensive carbonyl complexes as single electron transfer agents, photosensitizers, or hydrogen atom transfer agents.

1 Introduction

2 Homocoupling of Aryl Halides

3 Functionalization of C(sp³)–H Bonds

3.1 Dehydrogenation of Alkanes

3.2 Arylation/Alkylation

3.3 Carboxylation

3.4 Acylation

3.5 Hydroalkylation of Olefins

3.6 Hydroalkylation of Imines

4 Benzoylation of Aryl Bromides

5 Aryl Esterification

6 Oxidation of β-Keto Esters

7 Conclusions and Future Outlook

Key words

dual catalysis - carbonyl-photocatalysis - transition-metal catalysis - C–C bond - C–O bond

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See also:
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