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Synthesis 2024; 56(22): 3349-3364
DOI: 10.1055/s-0042-1751568
DOI: 10.1055/s-0042-1751568
short review
Dual Catalysis
Asymmetric Allylic Substitution Reactions Based on Relay Catalysis
We are grateful for funding from the National Natural Science Foundation of China (22001177), Shenzhen Bay Laboratory (S201100003 and S211101001-1), Shenzhen Bay Qihang Fellow (QH23001), and the Guangdong Pearl River Talents Program (2021QN020268).
Abstract
Transition-metal-catalyzed asymmetric allylic substitution reactions represent a hot research topic in the field of asymmetric synthesis, with significant progress having been made. Among diverse catalysis systems, relay catalysis enables sequential activation of multiple steps in one pot and the rapid construction of multiple chiral centers, providing a simple and powerful platform for organic synthesis. Recently, relay catalysis has been successfully applied to asymmetric allylic substitution reactions, and a variety of challenging transformations have been realized. This Short Review summarizes the related progress on asymmetric allylic substitution reactions based on relay catalysis over the last decade.
1 Introduction
2 The General Transformation Model
3 Allylation Relays Further Reaction
4 Initial Reaction Relays Allylation
5 Conclusion and Outlook
Key words
asymmetric catalysis - allylic substitution - relay catalysis - transition metal - asymmetric transformationPublication History
Received: 01 February 2024
Accepted after revision: 15 February 2024
Article published online:
05 March 2024
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For selected reviews on relay reactions, see:
For selected examples on relay reactions, see: