Trichloroisocyanuric Acid/NaNO2 as a Novel Heterogeneous System for the N-Nitrosation of N,N-Dialkylamines Under Mild Conditions

Mohammad Ali Zolfigol; Arash Ghorbani Choghamarani; Hassan Hazarkhani

doi:10.1055/s-2002-31897

LETTER

Trichloroisocyanuric Acid/NaNO₂ as a Novel Heterogeneous System for the N-Nitrosation of N,N-Dialkylamines Under Mild Conditions

Mohammad Ali Zolfigol*^a, Arash Ghorbani Choghamarani^a, Hassan Hazarkhani^b
^a Chemistry Department, College of Science, Bu-Ali Sina University, Hamadan, Zip Code 65174, Iran
^b Chemistry Department, Institute for Advanced Studies in Basic Sciences (IASBS), P. O. Box 45195-159, Gava Zang, Zanjan, Iran
e-Mail: Zolfi@basu.ac.ir;

Abstract

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Abstract

A combination of trichloroisocyanuric acid and sodium nitrite in the presence of wet SiO₂ was used as an effective nitrosating agent for the nitrosation of N,N-dialkyl amines to their corresponding nitroso derivatives under mild and heterogeneous conditions in moderate to excellent yields.

Key words

trichloroisocyanuric acid - nitrosation - secondary amines - N-nitroso amines

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References

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