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DOI: 10.1055/s-2002-35575
Polymer-Supported Hypervalent Iodine Reagents
Publication History
Received
2 January 2002
Publication Date:
20 November 2002 (online)


Abstract
Polymer-supported hypervalent iodine reagents, bearing (diacetoxy)iodo, (dihalo)iodo, (hydroxy)(tosyloxy)iodo, (hydroxy)(phosphoryloxy)iodo, aryliodonium, 1,2-benziodoxol-3-one, and hypervalent iodine groups as counter anions, can be used for various oxidative functional group conversions of substrates. These polymer species can be recovered quantitatively by simple filtration, and can be regenerated and reused. Thus, these polymer-supported hypervalent iodine reagents are very useful, effective, and environmentally benign reagents for organic synthesis.
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1 Introduction
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2 Polymer-Supported Reagents Bearing (Diacetoxy)iodo
Groups -
3 Polymer-Supported Reagents Bearing (Dihalo)iodo Groups
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4 Polymer-Supported Reagents Bearing (Hydroxy)(tosyl-
oxy)iodo Groups and (Hydroxy)(phosphoryloxy)iodo
Groups -
5 Polymer-Supported Reagents Bearing Aryliodonium
Groups -
6 Polymer-Supported Reagents Bearing 1,2-Benziodoxol-3-
one Groups -
7 Polymer-Supported Reagents Bearing Hypervalent Iodine
Groups as Counter Anion
Key words
polymer supported reagents - hypervalent iodine - oxidation