Mercury(II)-Catalyzed Regioselective Addition Reaction of Monoesters of Phosphonic Acid to Terminal Alkynes: Synthesis of Vinyl Phosphonates

Aiyun  Peng; Yixiang  Ding

doi:10.1055/s-2003-36818

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Mercury(II)-Catalyzed Regioselective Addition Reaction of Monoesters of Phosphonic Acid to Terminal Alkynes: Synthesis of Vinyl Phosphonates

Aiyun Peng, Yixiang Ding*
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China
e-Mail: dingyx@pub.sioc.ac.cn;

Abstract

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Abstract

Vinyl phosphonates 3a-l were prepared by the regioselective addition reaction of monoesters of phosphonic acid to alkynes in the presence of Hg(OAc)₂/BF₃·OEt₂.

Key words

mercury(II)-catalyzed - addition reaction - regioselective - vinyl phosphonate

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