Synlett 2003(3): 0382-0386
DOI: 10.1055/s-2003-37110
LETTER
© Georg Thieme Verlag Stuttgart · New York

A Convergent Construction of Quaternary Centres and Polycyclic Structures

Grégori Binot, Béatrice Quiclet-Sire, Twana Saleh, Samir Z. Zard*
Laboratoire de Synthèse Organique associé au CNRS, Ecole Polytechnique, 91128 Palaiseau, France
Fax: +33(1)69333851; e-Mail: zard@poly.polytechnique.fr;
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Publication History

Received 7 January 2003
Publication Date:
07 February 2003 (online)

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Abstract

Various xanthates, made by conjugate addition of xanthic acid to electrophilic olefins, add in a inter- or intra-molecular fashion to olefins allowing a direct introduction of a quaternary centres and the construction of polycyclic structures.